Experimental and Computational Evidence for the Participation of Nonclassical Dihydrogen Species in Proton Transfer Processes on Ru–Arene Complexes with Uncoordinated N Centers. Efficient Catalytic Deuterium Labeling of H2 with CD3OD

Gustavo Espino, Agustín Caballero, Blanca R. Manzano, Lucía Santos, Mercedes Pérez-Manrique, Miquel Moreno, and Félix A. Jalón*

 Organometallics, 2012, 31 (8), pp 3087–3100

DOI: 10.1021/om300015j